SIMULTANEOUS EXTRACTION AND POTENTIOMETRIC DETERMINATION OF POTASSIUM AND NITRATE IN SOIL BY USING ION SELECTIVE ELECTRODES
Abstract
Rapid and simultaneous determination of nitrate (NO-) and potassium (K+) ions in soil samples using ion selective electrodes (ISE) was investigated. The compatibility of ISEs with soil extraction solution is a challenging subject as various effects such as pH, ionic strength and interferences have to be considered as well as efficiency of the extraction solution. In this study, 30 agricultural soil samples of different properties were extracted with 0.01 mole.L-1 Al2(SO4)3 and the extracts were simultaneously measured by NO- - ISE and K+ - ISE in a flow system. The results were compared with ion chromatography (IC) as the reference method, and the regression analysis between IC and ISE results was yielded high correlation (R2 = 0.986 and R2 = 0.951 for K+ and NO3-, respectively). It was concluded that, ion selective electrodes can be used with 0.01 mole.L-1 Al2(SO4)3 extraction solution for rapid and simultaneous determination of nitrate and potassium in soil samples.
About the Authors
Karadag Sevin
Mir Arastirma ve Gelistirme A.S
Kazakhstan
Kazakhstan
Eren Emel
Mir Arastirma ve Gelistirme A.S
Kazakhstan
Kazakhstan
Vetinkaya Ebru
Mir Arastirma ve Gelistirme A.S
Kazakhstan
Kazakhstan
§enlikci All
Mir Arastirma ve Gelistirme A.S
Kazakhstan
Kazakhstan
Ozen Selin
Mir Arastirma ve Gelistirme A.S
Kazakhstan
Kazakhstan
Deveci Seda
Mir Arastirma ve Gelistirme A.S
Kazakhstan
Kazakhstan
References
1. Aitkenhead, M.J., Coull, M.C., Towers, W., Hudson, G., Black H.I.J., 2012. Predicting soil chemical composition and other soil parameters from field observations using a neural network, Computers and Electronics in Agriculture 82 (2012) 108-116.
2. Baranowski, R., Rybak, A., Baranowska, I., 2002. Speciation Analysis of Elements in Soil Samples by XRF. Polish Journal of Environmental Studies Vol. 11, No. 5 (2002), 473-482.
3. Bishop C. M., 1995. Neural Networks for Pattern Recognition. Clarendon Press, Oxford. Bortolon, L., Gianello, C., Welter, S., Almeida, R. G. O. and Giasson, E., 2011. Simultaneous Extraction of Phosphorus, Potassium, Calcium and Magnesium from Soils and Potassium
4. Recommendations for Crops in Southern Brazil. Pedosphere 21(3): 365-372.
5. Bortolon, L. and Gianello, C., 2010. Simultaneous Multielement Extraction With The Mehlich-1 Solution For Southern Brazilian Soils Determined By ICP-OES And The Effects On The Nutrients Recommendations To Crops. R. Bras. Ci. Solo, 34:125-132.
6. Bratovcic, A., Odobasic, A., Catic, S., 2009. The Advantages of the Use of IonSelective Potentiometry in Relation to UV/VIS Spectroscopy. Agriculturae Conspectus Scientificus, Vol. 74 (2009) No. 3 (139-142).
7. Campbell M. (1997). Sensor systems for environmental monitoring vol. 1. Blackie Academic & Professional, London.
8. Carey, C.M., and W.B. Riggan. 1994. Cyclic polyamine ionophores for use in a dibasic-phosphate-selective electrode. Anal. Chem. 66:3587-3591.
9. Chen, Z.L., R. De Marco, and P.W. Alexander. 1997. Flow-injection potentiometric detection ofphosphates using a metallic cobalt wire ionselective electrode. Anal. Commun. 34:93-95.
10. Ciesla, J., Ryzak, M., Bieganowski, A., Tkaczyk, P., Walczak, R.T, 2007. Use ofion-selective electrodes for determination of content of potassium in Egner-Rhiem soil extracts. RES. AGR. ENG., 53, 2007 (1): 29-33.
11. Durst R. A. (1969). Ion - Selective Electrodes. In: Durst RA (ed) Proceedings of a symposium at the National Bureau of Standards, Gaithersburg, Maryland.
12. Dursuna, M. and Ozden, S., 2014. An efficient improved photovoltaic irrigation system with artificial neural network based modeling of soil moisture distribution - A case study in Turkey, Computers and Electronics in Agriculture 102 (2014) 120-126.
13. Hartz, T. K., 1994. A quick test procedure for soil nitrate-nitrogen. Communications in Soil Science and Plant Analysis Volume 25, Issue 5-6: 511-515.
14. Kahveci, O., Atalay, i. Z., 2010. Ala§ehir ve Salihli Bag Topraklarinin Alinabilir Potasyum Analizlerinde Degi§tirilmi§ 1N NH4OAc Yontemine Alternatif Yontemlerin Belirlenmesi. Ege Univ. Ziraat Fak. Derg., 2010, 47 (3): 275-286.
15. Kalra, Y. P., 1998. Methods for Plant Analysis. CRC, USA. pp.85-88.
16. Kim, H. J., Hummel, J. W., Sudduth, K. A., Motavalli, P. P., 2007. Simultaneous Analysis of Soil Macronutrients Using Ion-Selective Electrodes. Soil Sci. Soc. Am. J. 71:1867-1877
17. Knoll, M., K. Cammann, C. Dumschat, M. Borchardt, and G. Hogg. 1994. Microfibre matrix-supported ion-selective PVC membranes. Sens. Actuators B 20:1-5.Levitchev, S., A. Smirnova, A. Bratov, and Y. Vlasov. 1998. Electrochemical properties of photocurable membranes for allsolid-state chemical sensors. Fresenius J. Anal. Chem. 361:252-254.
18. Liu, J.J., Li, S.P., Wang, Y.T., 2006. Optimization for quantitative determination of four flavonoids in Epimedium by capillary zone electrophoresis coupled with diode array detection using central composite design, Journal of Chromatography A, 1103(2) 344-349.
19. Madurapperuma, W. S. and Kumaragamage, D., 2008. Evaluation of Ammonium Bicarbonate-Diethylene Triamine Penta Acetic Acid as a Multinutrient Extractant for Acidic Lowland Rice Soils. Communications in Soil Science and Plant Analysis, 39: 1773-1790.
20. Matula, J., 2009. A Relationship between Multi-Nutrient Soil Tests (Mehlich 3, Ammonium Acetate, and Water Extraction) and Bioavailability of Nutrients from Soils for Barley. Plant Soil Environ., 55, 2009 (4): 173-180.
21. Morf, W.E. 1981. The Principles of Ion-Selective Electrodes and of Membrane Transport 2, Elsevier, Amsterdam.
22. Plank, C. O., 1992. Plant Analysis Reference Procedures for the Southern Region of the United States. Plant Anal. Ref. Proc. for S. US (SCSB # 368), pp. 23-27
23. Poonia, S. R. and Bhumbla, D. R., 1974. Effect of H2SO4, HCl and Al2(SO4)3 on The Yield, Chemical Composition and Ca Uptake From Applied Ca45CO3 by Dhaincha (Sesbania Aculeata Pers.) In A Saline Alkali Soil. Plant and Soil 40, 557-564 (1974).
24. Roth, G. W., Beegle, D. B., Fox, R. H., Toth J. D. and Piekielek W. P., 1991. Development of a quicktest kit method to measure soil nitrate. Communications in Soil Science and Plant Analysis, Volume 22, Issue 3-4: 191-200.
25. Smith G. R., 1975. Rapid Determination of Nitrate-Nitrogen in Soils and Plants with the Nitrate Electrode. Analytical Letters Volume 8, Issue 7: 503-508.
26. Soares, J.D.R,. Pasqual, M., Lacerda, W.S., Silva, S.O. , and Donato S.L.R., 2013. Utilization of artificial neural networks in the prediction of the bunches' weight in banana plants, Scientia Horticulturae 155 (2013) 24-29.
27. Taber H. G. and Killorn, R., 1993. Determination of nitrate in unfiltered extracts of musk-melon tissue by ion-selective electrodes. Communications in Soil Science and Plant Analysis, Volume 24, Issue 11-12: 1231-1241.
28. Tsukada, K., M. Sebata, Y. Miyahara, and H. Miyagi. 1989. Long-life multiple ISFETs with polymeric gates. Sens. Actuators 18: 329-336.
29. Wang, J. J., Harrell, D. L., Henderson, R. E. and Bell P. F., 2004. Comparison of Soil-Test Extractants for Phosphorus, Potassium, Calcium, Magnesium, Sodium, Zinc, Copper, Manganese, and Iron in Louisiana Soils. Communications in Soil Science And Plant Analysis, Vol. 35, Nos. 1 & 2, pp. 145-160.
30. Wang J. J., and Scott, A. D., 2001. Determination of exchangeable potassium in soil using ion-selective electrodes in soil suspensions. European Journal of Soil Science, 52,143-150.
31. Wroblewski, W., K. Wojciechowski, A. Dybko, Z. Brzozka, R.J.M. Egberink, B.H.M. Snellink-Ruel, and D.N. Reinhoudt. 2000. Uranyl salophenes as ionophores for phosphate-selective electrodes. Sens. Actuators B 68:313-318.
32. Xiao, D., H.Y. Yuan, J. Li, and R.Q. Yu. 1995. Surface-modified cobalt-based sensor as a phosphate-sensitive electrode. Anal. Chem. 67:288-291.
33. Zbiral, J. and Nemec, P., 2005. Comparison of Mehlich 2, Mehlich 3, Cal, Schachtschabel, 0.01M CaCl2 and Aqua Regia Extractants for Determination of Potassium in Soils.
34. Communications in Soil Science and Plant Analysis, 36: 795-803.
35. Zarifneshat, S., Rohani, A., Ghassemzadeh, H. R., Sadeghi, M., Ahmadi, E., Zarifneshat, M., 2012. Predictions of apple bruise volume using artificial neural network, Computers and Electronics in Agriculture 82 (2012) 75-86.
Review
For citations:
Sevin K., Emel E., Ebru V., All §., Selin O., Seda D. SIMULTANEOUS EXTRACTION AND POTENTIOMETRIC DETERMINATION OF POTASSIUM AND NITRATE IN SOIL BY USING ION SELECTIVE ELECTRODES. Soil Science and Agrichemistry. 2014;(4):69-77. (In Russ.)
Views:
75
Email this article 