kaz65Почвоведение и агрохимияSoil Science and Agrichemistry1999-740X2959-3433Казахский научно-исследовательский институт почвоведения и агрохимии имени У.У. Успановаkaz65-429Research ArticleSOIL CHEMISTRYKINETIC ADSORPTION OF AMMONIUM ONTO SOME LOESS SOILS OF NORTHERN IRANEsmaelDordipoure.dordipour@vahoo.comSafiyeCharkazinoemail@neicon.ruMojtabaBarani Motlaghnoemail@neicon.ruSaeedNasrolanezhadnoemail@neicon.ruDepartment of Soil Science, Gorgan University of Agricultural Sciences and Natural ResourcesKazakhstanDepartment of Plant Protection, Gorgan University of Agricultural Sciences and Natural ResourcesKazakhstan201407112022045562Copyright © Esmael D., Safiye C., Mojtaba B.M., Saeed N., 20222022Esmael D., Safiye C., Mojtaba B.M., Saeed N.Esmael D., Safiye C., Mojtaba B.M., Saeed N.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://journal.soil.kz/jour/article/view/429

Высокая адсорбция аммония наблюдалась в почве в Кордкоском районе, а низкая наблюдалась в почве в Хуттане 2. Степень адсорбции аммония во всех почвах можно лучше всего описать при помощи псевдо второго порядка, степенной функции и упрощенных уравнений Эловича.

The study of adsorption kinetics is very useful for understanding the mechanisms that are involved. In order to predict the mechanism involved during the present sorption process and the potential rate controlling steps such as mass transport, pore diffusion and chemical reaction processes, several kinetic models were used to fit the experimental data, namely, zero-order, first-order, pseudo-second-order, simplified Elovich, parabolic diffusion and power function models. At the present study, an ammonium adsorption kinetic experiment was conducted using solution containing 100 mg/l of ammonium chloride at the times of 0.25 to 384 h. Kinetic equations for ammonium adsorption were evaluated by comparing coefficients of determination (r2) and standard errors of estimate (SE) for each equation, which were determined by least square regression analysis. The results of adsorption kinetic study showed that ammonium is adsorbed fast within the first hours, but with elapsing the time, it will be slow. The most ammonium adsorption was in Kordkoy soil and the lowest one was observed in the Houttan soil 2. The rates of ammonium adsorption in all soils could be best described by the pseudo second order, power function and simplified Elovich equations.

AdsorptionammoniumkineticReferencesAzizian, A., 2004. Kinetic models of sorption: a theoretical analysis. J. Colloid Interface Sci. 276(1), 47-52.Azizian, A., 2004. Kinetic models of sorption: a theoretical analysis. J. Colloid Interface Sci. 276(1), 47-52.Bache, B.W., Williams, E.G., 1971. A phosphate sorption index for soils. J. Soil Sci. 22, 289-301.Bache, B.W., Williams, E.G., 1971. A phosphate sorption index for soils. J. Soil Sci. 22, 289-301.Bahreini Touhan, M., Dordipour, E., Movahedi Naeini, S.A., 2010. Kinetic of nonexchangeable potassium release using citric acid and CaCl2 in dominant farmlands soil series in Golestan province. J. Sci. Technol. Agric. Nat. Resour., Water Soil Sci. 14 (53), 113-127. (In Persian)Bahreini Touhan, M., Dordipour, E., Movahedi Naeini, S.A., 2010. Kinetic of nonexchangeable potassium release using citric acid and CaCl2 in dominant farmlands soil series in Golestan province. J. Sci. Technol. Agric. Nat. Resour., Water Soil Sci. 14 (53), 113-127. (In Persian)Chapman, H. D., 1965. Cation exchange capacity. In: Black, C.A., Evans, D.D., White, L.J., Ensminger, L.E., Clark, F.E. (Eds.), Methods of Soil Analysis. American Society of Agronomy, Madison, WI., pp. 891-901.Chapman, H. D., 1965. Cation exchange capacity. In: Black, C.A., Evans, D.D., White, L.J., Ensminger, L.E., Clark, F.E. (Eds.), Methods of Soil Analysis. American Society of Agronomy, Madison, WI., pp. 891-901.Chien, S.H., Clayton, W.R., 1980. Application of Elovich equation to the kinetics of phosphate release and sorption in soils. Soil Sci. Soc. Am. J. 44, 265-268.Chien, S.H., Clayton, W.R., 1980. Application of Elovich equation to the kinetics of phosphate release and sorption in soils. Soil Sci. Soc. Am. J. 44, 265-268.Everett, D.H., 1965. Interactions between adsorbed molecules. Discuss. Faraday Soc. 40, 177-187.Everett, D.H., 1965. Interactions between adsorbed molecules. Discuss. Faraday Soc. 40, 177-187.Farshadirad, A., Dordipour, E., Khormali1, F., 2012. Kinetics of non-exchangeable potassium release from soil and its components in some soils of Golestan province. J. Sci. Technol. Agric. Nat. Resour., Water Soil Sci. 16 (59), 273-285.Farshadirad, A., Dordipour, E., Khormali1, F., 2012. Kinetics of non-exchangeable potassium release from soil and its components in some soils of Golestan province. J. Sci. Technol. Agric. Nat. Resour., Water Soil Sci. 16 (59), 273-285.Feigenbaum, S., Edelstein, R., Shainberg, I., 1981. Release rate of potassium and structural cations from micas to ion exchangers in dilute solutions. Soil Sci. Soc. Am. J. 45, 501-506.Feigenbaum, S., Edelstein, R., Shainberg, I., 1981. Release rate of potassium and structural cations from micas to ion exchangers in dilute solutions. Soil Sci. Soc. Am. J. 45, 501-506.Gee, G.W., and Bauder, J.W. 1986. Particle-size analysis. In: Klute, A. (Ed.), Methods of Soil Analysis. Part I. Physical and Mineralogical Methods. 2nd ed. ASA, SSSA, Madison, WI. USA., pp. 383-411.Gee, G.W., and Bauder, J.W. 1986. Particle-size analysis. In: Klute, A. (Ed.), Methods of Soil Analysis. Part I. Physical and Mineralogical Methods. 2nd ed. ASA, SSSA, Madison, WI. USA., pp. 383-411.Guo, X.J., Zeng, L., Li, X.M., Park, H.S., 2008. Ammonium and potassium removal for anaerobically digested wastewater using natural clinoptilolite followed by membrane pretreatment. J. Hazard. Mater. 151, 125-133.Guo, X.J., Zeng, L., Li, X.M., Park, H.S., 2008. Ammonium and potassium removal for anaerobically digested wastewater using natural clinoptilolite followed by membrane pretreatment. J. Hazard. Mater. 151, 125-133.Hadas, A., Feigenbaum, S., Feigin, A., Portnoy, R., 1986. Distribution of nitrogen forms and availability indices in profiles of differently managed soil types. Soil Sci. Soc. Am. J. 50, 308313.Hadas, A., Feigenbaum, S., Feigin, A., Portnoy, R., 1986. Distribution of nitrogen forms and availability indices in profiles of differently managed soil types. Soil Sci. Soc. Am. J. 50, 308313.Havlin, J.L., Westfall, D.G., 1985. Potassium Release Kinetics and Plant Response in Calcareous Soils. Soil Sci. Soc. Am. J. 49, 366-370.Havlin, J.L., Westfall, D.G., 1985. Potassium Release Kinetics and Plant Response in Calcareous Soils. Soil Sci. Soc. Am. J. 49, 366-370.Havlin, J.L., Westfall, D.G., Olsen, R.S., 1985. Mathematical models potassium release kinetics in calcareous soils. Soil Sci. Soc. Am. J. 49, 371-376.Havlin, J.L., Westfall, D.G., Olsen, R.S., 1985. Mathematical models potassium release kinetics in calcareous soils. Soil Sci. Soc. Am. J. 49, 371-376.Ho, Y.S., McKay, G., 1994. Pseudo-second order model for sorption processes. Process Biochem. 34, 451-465.Ho, Y.S., McKay, G., 1994. Pseudo-second order model for sorption processes. Process Biochem. 34, 451-465.Huang, H., Xiao, X., Yan, B., Yang, L., 2010. Ammonium removal from aqueous solutions by using natural Chinese (Chende) zeolite as adsorbent. J. Haz. Mat. 175, 247-252.Huang, H., Xiao, X., Yan, B., Yang, L., 2010. Ammonium removal from aqueous solutions by using natural Chinese (Chende) zeolite as adsorbent. J. Haz. Mat. 175, 247-252.Keeney, D.R., Nelson, D.W., 1982. Nitrogen- Inorganic forms. In: Page, A. L., et al. (Eds.), Methods of soil analysis. Part 2. 2nd ed. Agron. Monogr. 9. ASA and SSSA, Madison, WI., USA., pp. P649-693.Keeney, D.R., Nelson, D.W., 1982. Nitrogen- Inorganic forms. In: Page, A. L., et al. (Eds.), Methods of soil analysis. Part 2. 2nd ed. Agron. Monogr. 9. ASA and SSSA, Madison, WI., USA., pp. P649-693.Kithome, M., Paul, J.W., Lavkulich, L.M., Bomke, A.A., 1998. Kinetics of ammonium adsorption and desorption by the natural zeolite clinoptilotite. Soil Sci. Soc. Am. J. 62, 622-629.Kithome, M., Paul, J.W., Lavkulich, L.M., Bomke, A.A., 1998. Kinetics of ammonium adsorption and desorption by the natural zeolite clinoptilotite. Soil Sci. Soc. Am. J. 62, 622-629.Kuo, S., Lotse, G., 1974. Kinetics of phosphate adsorption and desorption by hematite and gibbsite. Soil Sci. 116, 400-406.Kuo, S., Lotse, G., 1974. Kinetics of phosphate adsorption and desorption by hematite and gibbsite. Soil Sci. 116, 400-406.Lebedynets, M., Sprynskyy, M., Sakhnyuk, I., zbytniewski, R., Golembiewski, R., Buszewski, B., 2004. Adsorption of ammonium ions onto a natural zeolite: Transcarpathian Clinoptilolite. Adsorpt. Sci. Technol. 22 (9), 731 -741.Lebedynets, M., Sprynskyy, M., Sakhnyuk, I., zbytniewski, R., Golembiewski, R., Buszewski, B., 2004. Adsorption of ammonium ions onto a natural zeolite: Transcarpathian Clinoptilolite. Adsorpt. Sci. Technol. 22 (9), 731 -741.Lei, L.C., Li, X.J., Zhang, X.W., 2008. Ammonium removal from aqueous solutions using microwave-treated natural Chinese zeolite. Sep. Purif. Technol. 58, 359-366.Lei, L.C., Li, X.J., Zhang, X.W., 2008. Ammonium removal from aqueous solutions using microwave-treated natural Chinese zeolite. Sep. Purif. Technol. 58, 359-366.Liu, H., Dong, Y., Wang, H., Liu, Y., 2010. Ammonium adsorption from aqueous solutions by strawberry leaf powder: Equilibrium, Kinetic and effects of coexisting. Desalination 263, 70-75. Martin, H.W., Sparks, D.L., 1983. Kinetics of nonexchangeable potassium release from two coastal plain soils. Soil Sci. Soc. Am. J. 47, 883-887.Liu, H., Dong, Y., Wang, H., Liu, Y., 2010. Ammonium adsorption from aqueous solutions by strawberry leaf powder: Equilibrium, Kinetic and effects of coexisting. Desalination 263, 70-75. Martin, H.W., Sparks, D.L., 1983. Kinetics of nonexchangeable potassium release from two coastal plain soils. Soil Sci. Soc. Am. J. 47, 883-887.Moussavi, Gh., Talebi, S., Farrokhi, M., Sabouti, R.M., 2011. The investigation of mechanism, kinetic and isotherm of ammonia and humic acid co-adsorption onto natural zeolite. Chem. Eng. J. 171, 1159-1169.Moussavi, Gh., Talebi, S., Farrokhi, M., Sabouti, R.M., 2011. The investigation of mechanism, kinetic and isotherm of ammonia and humic acid co-adsorption onto natural zeolite. Chem. Eng. J. 171, 1159-1169.Muljadi, D., Posner, A.M., Quirk, J.P., 1966a. The mechanism of phosphate adsorption by kaolinite, gibbsite and pseudoboehmite. Part I. The isotherms and the effect of pH on adsorption. J. Soil Sci. 17, 212-229.Muljadi, D., Posner, A.M., Quirk, J.P., 1966a. The mechanism of phosphate adsorption by kaolinite, gibbsite and pseudoboehmite. Part I. The isotherms and the effect of pH on adsorption. J. Soil Sci. 17, 212-229.Muljadi, D., Posner, A.M., Quirk, J.P., 1966b. The mechanism of phosphate adsorption by kaolinite, gibbsite and pseudoboehmite. Part II. The location of the adsorption sites. J. Soil Sci. 17,230-237.Muljadi, D., Posner, A.M., Quirk, J.P., 1966b. The mechanism of phosphate adsorption by kaolinite, gibbsite and pseudoboehmite. Part II. The location of the adsorption sites. J. Soil Sci. 17,230-237.Nelson, R.E., 1982. Carbonate and gypsum. In: Page, A.L. (Eds.), Methods of Soil Analysis. Part 2. Chemical and Microbiological Properties. American Society of Agronomy/Soil Science Society of America, Madison, Wisconsin, USA., pp. 181-197.Nelson, R.E., 1982. Carbonate and gypsum. In: Page, A.L. (Eds.), Methods of Soil Analysis. Part 2. Chemical and Microbiological Properties. American Society of Agronomy/Soil Science Society of America, Madison, Wisconsin, USA., pp. 181-197.Nelson, D.W., Sommers. L. E., 1982. Total carbon, organic carbon and organic matter. In: Page, A. L. et al. (Eds.), Methods of soil analysis. Part 2. 2nd ed. ASA. SSSA. Madison, WI. USA, pp. 539-579.Nelson, D.W., Sommers. L. E., 1982. Total carbon, organic carbon and organic matter. In: Page, A. L. et al. (Eds.), Methods of soil analysis. Part 2. 2nd ed. ASA. SSSA. Madison, WI. USA, pp. 539-579.Oustan, Sh., 2004. Environmental Soil chemistry. Tabriz Univ. Press, Iran. (In Persian). Parravano, G., Boudant, M., 1955. Chemisorption and catalysis on oxide semiconductors. In: Frankenburg, W.G., et al. (Eds.), Advances in catalysis. Academic Press, New York., P47.Oustan, Sh., 2004. Environmental Soil chemistry. Tabriz Univ. Press, Iran. (In Persian). Parravano, G., Boudant, M., 1955. Chemisorption and catalysis on oxide semiconductors. In: Frankenburg, W.G., et al. (Eds.), Advances in catalysis. Academic Press, New York., P47.Rowell, D.L., 1995. Soil Science: Methods and Applications. Longman Scientific and Technical, Harlow, UK.Rowell, D.L., 1995. Soil Science: Methods and Applications. Longman Scientific and Technical, Harlow, UK.Sharpley, A.N., 1983. Effect of soil properties on the kinetics of phosphorus desorption. Soil Sci. Soc. Am. J. 47, 462-467.Sharpley, A.N., 1983. Effect of soil properties on the kinetics of phosphorus desorption. Soil Sci. Soc. Am. J. 47, 462-467.Sparks, D.L., 1986. Kinetics of reactions in pure and mixed systems. In: Sparks, D.L. (Ed.), Soil physical chemistry. CRC Press, Boca Raton, FL., pp. 83-145.Sparks, D.L., 1986. Kinetics of reactions in pure and mixed systems. In: Sparks, D.L. (Ed.), Soil physical chemistry. CRC Press, Boca Raton, FL., pp. 83-145.Sparks, D.L., 1989. Kinetics of soil chemical process. Academic Press. San Diego. California. USA.Sparks, D.L., 1989. Kinetics of soil chemical process. Academic Press. San Diego. California. USA.Sparks, D.L., 2000. Kinetics and mechanisms of soil chemical reactions. In: Summer, M. E. (Ed.), Handbook of soil science. CRC Press Inc. Boca Raton Florida. USA, pp. 123-168.Sparks, D.L., 2000. Kinetics and mechanisms of soil chemical reactions. In: Summer, M. E. (Ed.), Handbook of soil science. CRC Press Inc. Boca Raton Florida. USA, pp. 123-168.Sparks, D.L., Huang, P.M., 1985. The physical chemistry of soil potassium. In: Munson, R. (Ed.), Potassium in Agriculture. ASA, CSSA, SSSA and Madison, WI., pp. 202-276.Sparks, D.L., Huang, P.M., 1985. The physical chemistry of soil potassium. In: Munson, R. (Ed.), Potassium in Agriculture. ASA, CSSA, SSSA and Madison, WI., pp. 202-276.Steffens, D., Sparks, D.L., 1997. Kinetics of nonexchangeable ammonium release from soils. Soil Sci. Soc. Am. J. 61, 455-462.Steffens, D., Sparks, D.L., 1997. Kinetics of nonexchangeable ammonium release from soils. Soil Sci. Soc. Am. J. 61, 455-462.Ugurlu, M., Karaoglu, M.H., 2011. Adsorption of ammonium from an aqueous solution by fly ash and sepiolite: Isotherm, kinetic and thermodynamic analysis. Microporous and Mesoporous Mater. 139, 173-178.Ugurlu, M., Karaoglu, M.H., 2011. Adsorption of ammonium from an aqueous solution by fly ash and sepiolite: Isotherm, kinetic and thermodynamic analysis. Microporous and Mesoporous Mater. 139, 173-178.Ungarish, M., Aharoni, C., 1981. Kinetics of chemisorption: Deducing kinetic laws from experimental data. J. Chem. Soc. Faraday Trans. 77, 975-979.Ungarish, M., Aharoni, C., 1981. Kinetics of chemisorption: Deducing kinetic laws from experimental data. J. Chem. Soc. Faraday Trans. 77, 975-979.Wahab, M.A., Jellali, S., Jedidi, N., 2010. Ammonium biosorption onto sawdust: FTIR analysis, kinetics and adsorption isotherms modeling. Bioresour. Technol. 101, 5070-5075.Wahab, M.A., Jellali, S., Jedidi, N., 2010. Ammonium biosorption onto sawdust: FTIR analysis, kinetics and adsorption isotherms modeling. Bioresour. Technol. 101, 5070-5075.Wen, D.H., Ho, Y.S., Tang, X.Y., 2006. Comparative sorption kinetic studies of ammonium onto zeolite. J. Hazard. Mater. 133, 252-256.Wen, D.H., Ho, Y.S., Tang, X.Y., 2006. Comparative sorption kinetic studies of ammonium onto zeolite. J. Hazard. Mater. 133, 252-256.Yasrebi, J., Karimian, N., 1995. Distribution of nitrogen different forms in soils beneath the Doroudzan dam of Fars province. In: SSSI (Ed.), Proceedings ofthe 3rd Congress of Soil Science, Karaj, Iran, pp. 2.108-117.Yasrebi, J., Karimian, N., 1995. Distribution of nitrogen different forms in soils beneath the Doroudzan dam of Fars province. In: SSSI (Ed.), Proceedings ofthe 3rd Congress of Soil Science, Karaj, Iran, pp. 2.108-117.Zhang, Y.Z., 2006. Fixed ammonium content and maximum capacity of ammonium fixation in major types of tillage soils in Hunan province, China. Agriccultural Sciences in China, 6 (4), 466-474.Zhang, Y.Z., 2006. Fixed ammonium content and maximum capacity of ammonium fixation in major types of tillage soils in Hunan province, China. Agriccultural Sciences in China, 6 (4), 466-474.Zheng, H., Han, L.J., Ma, H.W., Zheng, Y., Zhang, H.M., Liu, D.H., Liang, S.P., 2008. Adsorption characteristics of ammonium ion by zeolite 13X. J. Hazard. Mater. 158, 577-584.Zheng, H., Han, L.J., Ma, H.W., Zheng, Y., Zhang, H.M., Liu, D.H., Liang, S.P., 2008. Adsorption characteristics of ammonium ion by zeolite 13X. J. Hazard. Mater. 158, 577-584.Zhu, W. L., Cui, L. H., Ouyang, Y., Long, C. F. Tang, X. D., 2011. Kinetic adsorption of ammonium nitrogen by substrate materials for constructed wetlands. Pedosphere. 21, 4. 454-463.Zhu, W. L., Cui, L. H., Ouyang, Y., Long, C. F. Tang, X. D., 2011. Kinetic adsorption of ammonium nitrogen by substrate materials for constructed wetlands. Pedosphere. 21, 4. 454-463.

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